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FIRST: Water found on Moon PDF E-mail
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by William Atkins   
Thursday, 10 July 2008
A U.S.-French team used new methods to analyze 40-year-old Apollo lunar samples that had previously shown no evidence of water. However, using more advanced instruments, the research team was able to detect very small amounts of water in the samples. The momentous announcement heralds the first time water has been discovered in materials from the Moon.


The research team consisted of American scientists from Brown University (Providence, Rhode Island), Carnegie Institution for Science (Washington, D.C.), and Case Western Reserve University (Cleveland, Ohio), along with French engineers from Cameca Instruments.

The press release by Erik Hauri, of the Department of Terrestrial Magnetism, Carnegie Institution for Science, appears in the EurekAlert article: “Moon water discovered: Dampens Moon-formation theory

Hauri led in the effort to develop the new techniques that allowed the group to detect the extremely small amounts of water in glasses and minerals of the lunar samples.

The discovery by the team is important because scientists have looked for water in lunar materials for nearly forty years, since Apollo 11 touched down on the Moon in 1969. However, they have been unable to find it due to the inability of technology, so most lunar scientists had concluded that moon rocks do not contain water.

The new technique called SIMS was able to measure molecules within the lunar samples that were on the order to two magnitudes lower than with past techniques. The technique is able to discern down to four or five water molecules per million, what is usually called parts per million (ppm).

In actuality, the members found up to 46 parts per million of water molecules in the tiny volcanic glass beads brought back from the Moon in the lunar samples.

Haui stated, "For the past four decades, the limit for detecting water in lunar samples was about 50 parts per million (ppm) at best. We developed a way to detect as little as 5 ppm of water. We were really surprised to find a great deal more in these tiny glass beads, up to 46 ppm."

Also making the discovery possible was the work of engineers from Cameca Instruments, who manufactured the NanoSIMS instrument that made the measurements of the lunar materials. The Cameca NanoSIMS instrument is an ion microprobe that was designed to measure ultra-fine features of trace elements and isotopes.

The technology used by the Cameca group is a refinement of a technique secondary ion mass spectrometry (SIMS). The SIMS technique allows for the composition of solid surfaces and thin films to be measured by "sputtering" (depositing while in vacuum) the surface with a focused “primary” (cesium) ion beam and, then, collecting and analyzing the secondary ions that are ejected.

The lunar samples used for this first-ever discovery of water on the Moon came from Moon rocks scooped up by astronauts on two NASA Apollo Moon missions.

Within the Moon rocks were tiny beads of volcanic glass. These glasses actually contained the water. Most of the water was found in the middle portion of the glass volume, and less in the outer portions of it.

The fact that water was found in higher concentrations in the middle of the glass beads than its outer volume tells scientists that most of the water on the Moon was lost during volcanic activity on the Moon.

Additional information about the results of this study are on page 2.



 
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